Graphite in an archaeological context comparing to other black substances – research problems and prospects

Autor

DOI:

https://doi.org/10.15584/anarres.2020.15.2

Słowa kluczowe:

black substances, black layers, graphite, archaeology, fingerprints

Abstrakt

In the archaeological context, substances with a black color have been extensively used in many ancient communities, in the form of items and layers, with the use of biogenic and mineral substances, and requiring a separate methodological approach. Each of them behaves differently in technological and postdepositional processes. The potential degree of the complexity of intentionally applied layers (e.g. paints or cosmetics) and the overlap of secondary substances and crusts, increases difficulties in obtaining unambiguous results and their interpretation. Graphite plays an important role among them. Several areas of the current use of graphite are, or at least could be, commonly shared in the present and in the past, and thus their analysis could be inspiring for archaeology and archaeometry. Graphite fingerprint and potential fingerprints are discussed in terms of their variability. The problem of graphitization as a potential source of misleading interpretation is discussed.

Bibliografia

Abłamowicz D. and Karwowski Ł., 2009. Production of graphite vessels by the Lusatian Culture population (in Polish, with English summary). In L. Domańska, P. Kittel and J. Forysiak (eds.), Środowiskowe uwarunkowania lokalizacji osadnictwa (= Środowisko – Człowiek – Cywilizacja 2). Poznań: Bogucki Wydawnictwo Naukowe, 377–387.

Aucoutourier M., Mathis F., Robcis D., Castaing J., Salomon J., Pichon L., Delange E. and Descamps S. 2010. Intentional patina on metal archaeological artefacts: non-destructive investigation of Egyptian and Roman museum treasures. Corrosion, Engineering and Science Technology 45(5), 314–321.

Bacon G.E. 1952. The reduction of the crystalline perfection of graphite by grinding. Acta Crystallographica 5, 392.

Baczyńska B. and Lityńska-Zając M., 2005. Application of Lithospermum officinale L. in early Bronze Age medicine. Vegetation History and Archaeobotany 14, 77–80.

Barrenechea J.F., Luque F.J., Millward D., Ortega L., Beyssac O. and Rodas M., 2009. Graphite morphologies from the Borrowdale deposit (NW England, UK): Raman and SIMS data. Contributions to Mineralogy and Petrology 158(1), 37–51.

Beyssac, Goffe, Chopin and Rouzaud. 2002. Raman spectra of carbonaceous material in metasediments. Journal of Metamorphic Geology 20, 859–871.

Bhattacharyya A., Schenk J., Rantitsch G., Thaler C. and Stocker H. 2015. Effect of alkaline elements on the reactivity, strenght and structural properties of blast furnace cokes. Metalurgija 54, 503–506.

Bothe C. I. 2007. Asphalt. In B.H. Berrie (ed.), Artistst’ Pigments. A Handbook of Their History and Characteristics 4. London: Washington and Archetype Publications, 1–38.

Caplete J.N. and Schindler M. 2018. Black rock-coatings in trial, British Columbia. Canada: Records of past emissions of lead, zinc, antimony, arsenic, tellurium, tin, selenium, silver, bismuth and indium-bearing atmospheric contaminants. Canadian Mineralogist 56, 113–127.

Chalmin E., Farges F., Vignaud C., Susini J., Menu M. and Brown Jr. G.E. 2007. Discovery of Unusual Minerals in Paleolithic Black Pigments from Lascaux (France) and Ekain (Spain). American Institute of Physics Conference Proceedings, 220–222.

Chaundri S.K. and Jain N.K. 2009. History of cosmetics. Asian Journal of Pharmaceutics 3(3), 164–167.

Cohen-Ofri I., Weiner L., Boaretto E., Mintz G. and Weiner S. 2006. Modern and fossil charcoal: aspects of structure and diagenesis. Journal of Archaeological Science 33, 428–439.

Colombini M.P. and Modugno F. 2009. Organic Materials in Art and Archaeology. In M.P. Colombini and F. Modugno (eds.), Organic Mass Spectrometry in Art and Archaeology. Oxford: Wiley&Sons, 36.

Connan J. 1999. Use and trade of bitumen in antiquity and prehistory: molecular archaeology reveals secrets of past civilisations. Philosophical Transactions of the Royal Society B 354, 33–50.

Craig, O., Saul, H., Lucquin, A., Nishida Y., Tache K., Clarke L., Thompson A., Altoft D.T., Uchiyama J., Ajimoto M., Gibbs K., Isaksson S., Heron C.P. and Jorgan P. 2013. Earliest evidence for the use of pottery. Nature 496, 351–354.

Cvikel D., Mentovivh E.D., Ashkenazi D., and Kahanov Y., 2013. Casting techniques of cannonballs from the Akko 1 shipwreck: Archaeometallurgical investigations. Journal of Mining and Metallurgy. Section B: Metallurgy 49(1), 107–119.

Delarue F., Rouzaud J-N., Derenne S., Bourbin M., Westall F., Kremer B., Sugitani K., Deldicque D. and Robert F. 2016. The Raman-Derived Carbonization Continuum: A Tool to Select the Best Preserved Molecular Structures in Archaean Kerogens. Astrobiology 16(6), 407–417.

Demakopoulou K., Mangou E., Jones R.E. and Photos-Jones E. 1995. Mycenaean black inlaid metalware in the National Archaeological Museum Athens: a technical examination. Annual of the British School at Athens 90, 137–153.

Demetrykiewicz W., 1897. Cmentarzyska i osady przedhistoryczne w okolicy Tarnobrzega i Rozwadowa nad Sanem/Cemeteries and prehistoric settlements in the area of Tarnobrzeg and Rozwadow on the San. Kraków: Akademia Umiejętności.

Druc I. 2001. Soil sources for ceramic production in the Andes. In I. Druc (ed.), Archaeology and Clays (= British Archaeological Reports. International Series 942). Oxford: Archaeopress, 1–12.

Dulęba P., Okoński J., Przybyła M. M. and Suchorska-Rola M. 2012. Ostatnie sezony badań na terenie kompleksu stanowisk Zagorze 2 – Staniątki 26, gm. Niepołomice, woj. małopolskie/Last seasons of research in the Zagorze 2 site complex – Staniątki 26, commune Niepołomice, voivodeship Lesser. In S. Kadrow (ed.), Raport 2007–2008 1. Warszawa: Narodowy Instytut Dziedzictwa, 321–342.

Eastaugh N., Walsch V., Chaplin T. and Siddal R. 2005. Pigment Compendium. A Dictionary of Historical Pigments. Amsterdam: Elsevier.

Fayos J. 1999. Possible 3D carbon structures as progressive intermediates in graphite to diamond. Journal of Solid State Chemistry 148(2), 278–285.

Gebhard R., Bott R., Distler N., Michalek J., Riederer J., Wagner F.E. and Wagner U., 2004. Ceramics from the Celtic opiidum of Manching and its influence in Central Europe. Hyperfine Inteactions 154, 199-241.

Gjostein-Resi H. 2005. Archaeological Finds of Jet from Norway. Signs of continuous contacts westwards in the Viking and Medieval Periods? Collegium Medievale 18 (ojs.novus.no)

Gliozzo E., Kirkman I.W., Pantos E., M. and Memmi Turbanti I. 2004. Black gloss pottery. Production sites and technology in northern Etruria, Part II: Gloss technology. Archaeometry 46 (2), 227-246.

Gradziński M., Górny A., Pazdur A., Pazdur M.F., 2003. Origin of black coloured laminae in speleothems in the Kraków – Wieluń Upland, Poland. Boreas 32, 532-542.

Groot N.C.F., Dik J., Van der Kooij P., Alkemade P.F.A., Sivel V.G.M., Tichelaar F.G. 2006. Dark and shiny: The discovery of chromite in Bronze Age faience. Archaeometry 48( 2), 229-236.

Hahn-Weinheimer P. and Hirner A. 1981. Isotopic evidence for the origin of graphite. Geochemical Journal 15, 9-15.

Hamilton L.H., Ramsden A.R., Stephens F.J., 1970. Fossiliferous graphite from Undercliff, New South Wales. Journal of the Geological Society of Australia 17(1), 31-37.

Harrel J.A. and Lewan M.D., 2002. Sources of mummy bitumen in ancient Egypt and Palestine Archaeometry 44 (2), 285-293.

Havancsák I., Fekete J. and Bajnóczi B. 2011. Carbon isotope study on Celtic-graphite tempered archaeological ceramics from the South Transdanubian region (Hungary). Central European Geology 54 (1-2), 75-79.

Hexter M.R. and Hopwood W.R. 1992. Investigation of decorative coating on Kongo ceramics Using UV Light and FTIR analysis. Materials issues in art and archaeology III : symposium held in April 27-May 1, 1992, San Francisco, California, U.S.A., 291-307.

Hlava M. 2008. Grafit v době laténské na Moravě/Graphite in the La Tène period in Moravia. Památky Archeologické 99, 189-258.

Houzar S.and Šrein V., 2000. Variation in chemical composition of V-bearing muscovite dring metamorphic evolution of graphitic quartzites in the Moravian Moldanubicum. Journal of the Czech Geological Society 45, 143-148.

Jaszczak J.A., Dimovski S., Hackney S.A., Robinson G.W., Bosio P. and Gogotsi Y. 2007. Micro-and nanoscale graphite cones and tubes from Hackman Valley, Kola Peninsula, Russia.Canadian Mineralogist 45, 379-389.

Jeong G.Y., Kim S.J. and Chang S.J. 2003. Black carbon pollution of speleothems by fine urban aerosols in tourists caves. American Mineralogist 88, 1872-1878.

Klíma B. 1956. Coal in the Ice Age: The Excavation of a Palaeolithic Settlement at Ostrava-Petřkovice in Silesia. Antiquity 20, 118, 98-101.

Kostoglou M. and Navasaitis J. 2006. Cast iron in ancient Greece: myth or fact? Meditteranean Archeology and Archaeometry 6, 2, 55-58.

Kotowiecki A. 2004. Artefacts in Polish collections made of meteoritic iron. Meteoritics and Planetary Science 39, Supplement 8, A151-A156.

Kreiter A., Szabolcs C., Bendő Z., Imre J.E., Pánczél P. and Váczi G. 2014. Shine like metal: an experimental approach to understand prehistoric graphite coated pottery technology. Journal of Archaeological Science 52, 129-142.

Kwiecińska B. and Petersen H.I., 2004. Graphite, semi-graphite, natural coke, and natural char classification – ICCP system. Coal Geology 57, 99-116.

Kwiecińska B. and Szpunar J., 1970. Badania tekstury grafitów metodą dyfrakcji neutronów. Mineralogia Polonica 1, 61-72.

Kwiecińska B., Wirska-Parachoniak M. and Parachoniak W., 1970. Zastosowanie transmisyjnej mikroskopii elektronowej w badaniach nad tzw. grafitową ceramiką celtycką/The use of transmission electron microscopy in research on the so-called graphite Celtic ceramics. Ochrona Zabytków 23(4), 315-320.

Lahijani P., Zainal Z.A., Mohammadi M. and Mohamed A.R. 2015. Conversion of the greenhouse gas CO2 to the fuel gas CO via the Boudouard reaction: A review. Renewable and Sustainable Energy Reviews 41, 615-632.

Laves F. and Baskin Y. 1956. On the formation of the rhomboedral graphite modification. Zeitschrift für Kristallographie 107, 337-356.

Lee S-M., Kang D-S and Roh J-S. 2015. Bulk graphite: materials and manufactiring process. Carbon Letters 16 (3), 135-146.

Lipson H.S. and Stokes A.R. 1942. The Structure of Graphite. Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences 181, 101–105.

Lis J. and Sylwestrzak H. 1986. Minerały Dolnego Śląska/Minerals of the Lower Silesia. Warszawa: Wydawnictwa Geologiczne.

Liu S., Zeng T.H., Hofmann M., Burcombe E., Wei J., Jiang R., Kong J. and Chen Y. 2011. Antubacterial Activity of Graphite, Graphite Oxide and Reduced Graphite Oxide: Membrane and Oxidative Stress. American Chemical Society 5 (9) , 6971-6970.

Luque F.J., Pasteris J.D., Wopenka B., Rodas M. and Barrenechea J.F. 1998. Natural fluid-deposited graphite: mineralogical characteristics and mechanism of formation. American Journal of Science 298, 471-498.

Łaciak D. and Stoksik H. 2010. Problematyka ceramiki malowanej i „grafitowanej” z wczesnej epoki żelaza w świetle badań fizykochemicznych/The problems of painted and "graphited" ceramics from the early Iron Age in the light of physicochemical research. Przegląd Archeologiczny 58, 105-146.

Łaciak D., Markiewicz M., Łydżba-Kopczyńska B., Gediga B., August C., Hojniak M., Rusek G. and Miazga B. 2017. Rekonstruowanie procesu wytwórczego ceramiki – badania nad halsztacką ceramiką malowaną z cmentarzyska w Domasławiu, stan. 10/11/12, po wrocławski. In S. Siemianowska, P. Rzeźnik and K. Chrzan ( EDS.), Ceramika i szkło w archeologii i konserwacji, Wrocław : Instytut Archeologii i Etnologii Polskiej Akademii Nauk, Ośrodek Badań nad Kulturą Późnego Antyku i Wczesnego Średniowiecza, 179-208.

Łaciak D., Borowski M., Łydżba-Kopczyńska B., Baron J. and Furmanek M. 2019. Archaeometric characterisation and origin of black coatings on prehistoric pottery. Geochemistry 79 (3), 453-466 https://doi.org/10.1016/j.chemer.2019.07.004.

Mahaney W., Kalm V., Dirszovsky R., Milner M., Sodhi R., Beukens R., Dorn R., Tricart P., Schwartz S.and Chamorro-Perez E. 2008. Hannibal’s trek across the Alps: Geomorphological analysis of sites of geoarchaeological interests. Meditterranean Archaeology and Archaeometry 8 (2), 39-54.

Martinón-Torres M., Rehren T. and Osten S. 2003. A 16th century lab in a 21th century lab: archaeometric study of the laboratory equipment from Oberstockstall (Kirchberg am Wagram,Austria). Antiquity 77, 298, 1-9.

Mukhopadhyay P. and Gupta R.K. 2013. Graphite, graphene and their polymer nanocomposytes. Boca Raton, FL : CRC Press.

Ohtomo Y., Kakegawa T., Ishida A., Nagase T. and Rosing M.T. 2013. Evidence for biogenic graphite in early Archaean Isua metasedimentary rocks. Nature Geosciense 7, 25-28 DOI:10.1038/NGEO2025, 1-4.

Parthasaradhy G., Sreedhar B. and Chetty T.R.K. 2007. Spectroscopic and X-ray diffraction studies on fluid deposited rhomboedral graphite from the Eastern Ghats Mobile Belt, India. Current

Science 90 (7), 995-1000.

Pasteris J.D. and Wopenka B. 1991. Raman spectra of graphite as indicators of metamorphism. Canadian Mineralogist 29 (1), 1-9.

Pawlikowski M. and Karwowski M. 2017. Mineralogical examination of graphite (?) pottery. Example – valley settlement in Thunau am Kamp, Lower Austria. Auxiliary sciences in archaeology, preservation of relics and environmental engineering 23, 1-10.

Pikirayi I. 2007. Ceramics and group identities. Towards a social archaeology in southern African Iron Age ceramic studies. Journal of Social Archaeology 7 (3), 286-301.

Pimenta M. A., Dresselhaus G., Dresselhaus M.S., Cancado L.G., Jorio A. and Saito R. 2007. Studying disorder in graphite-based systems by Raman spectroscopy. Physical ChemistryChemical Physics 9, 1276-1291.

Poleska P. 2006. Celtycki mikroregion osadniczy w rejonie podKrakówskim ( = Biblioteka Muzeum Archeologicznego w Krakówie 2). Kraków : Muzeum Archeologiczne w Krakówie.

Rantitsch G., Lämmerer W., Fisslthaler E., Mitschke S. and Kaltenböck H. 2016. On the discrimination of graphite and semi-graphite by Raman spectroscopy. Journal of Coal Geology 159, 48-56.

Reich S. and Thomsen C. 2004. Raman spectroscopy of graphite. Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences 362, 2271–2288.

Rodriguez S., Marques M., Suárez-Ruiz I., Camean I., Flores D. and Kwiecińska B. 2013. Microstructural investigations of natural and synthetic graphites and semi-graphites. International Journal of Coal Geology 111, 67-79.

Rodriguez S.,Suárez-Ruiz I., Marques M., Flores D., Camean I. and Garcia A.B. 2011. Development of graphite-like particles from the high temperature treatment of carbonized anthracites. International Journal of Coal Geology 85, 219-226.

Schindler M. and Dorn R.I. 2017. Coatings on Rocks and Minerals: The Interface Between the Litosphere and the Biosphere, Hydrosphere and Atmosphere. Elements. An International Magazine of Mineralogy, Geochemistry and Petrology 13 (3), 155-158.

Schrauder M., Beran A., Hoernes S. and Richter W. 1993. Constraints on the Origin and the Genesis of Graphite-Bearing Rocks From the Variegated Sequence of the Bohemian Massive (Austria). Mineralogy and Petrology 49, 175-188.

Sekine T. and Sato T. 1993. Shockinduced mechanism of phase transformation from rhomboidal BN to cubic BN. Journal of Applied Physics 74, 2440-2444.

Smirnov W. I. 1986. Geologia złóż kopalin użytecznych. Warszawa: Wydawnictwa Geologiczne.

Smith A.H.V. 2005. Coal microscopy in the service of archaeology. Coal Geology 62, 49-59.

Tamashausky A.V. 2006. An Introduction to Synthetic Graphite. Available from: https://asbury.com.

Tamashausky A.V. 2003. Graphite: a multifunctional additive for paint and coatings. Available from: https://asbury.com.

Tapsoba I., Arbault S., Walter P. and Armatore C. 2010. Finding Out Egyptian Gods’ Secret Using Analytical Chemistry: Biomedical Properties of Egyptian Black Makeup Revealed by Amperometry at Single Cells. Analytical Chemistry 82, 2, 457-460.

Teichmüller M. 1992. Organic petrology in the service of archaeology. International Journal of Coal Geology 20 (1-2), 1-21.

Teichmüller R. and Teichmüller M. 1986. Relations between coalification and palaeogeothermics in Variscan and Alpidic foredeeps of western Europe. Paleogeothermics 5, 53-78.

Touzain P., Balasooriya N., Bandaranayake K. abd Descolas-Gros C., 2010. Vein graphite from the Bogala and Kolongaha mines – Sri Lanka: A possible origin. Canadian Mineralogist 48, 1373- 1384.

Trawicka E. and Ceynowa B. 2011. Gdańsk w Europie, Europa w Gdańsku. Kontakty handlowe i kulturowe Gdańska w świetle wykopalisk archeologicznych. Katalog wystawy. Gdańsk : Muzeum Archeologiczne w Gdańsku.

Trąbska J., Wesełucha-Birczyńska A., Trybalska B. and Gaweł A. 2017. The surface of the artefact. In T. Płonka and K. Kowalski (eds.): Rusinowo. The Symbolic Culture of Foragers in the Late Palaeolithic and the Early Mesolithic. Wrocław : University of Wrocław. Institute of Archaeology, 119–146.

Trąbska J., Oliva M., Gaweł A. and Trybalska B. 2016. Dolní Vĕstonice I female grave. Red colourants and other components of the burial fill and grave floor. Studia Praehistorica Belgica 8. Anthropologica et Praehistorica 126, 161-178.

Trąbska J., Trybalska B. 2014. True and fake red layers on the objects from archaeological and historical context: microscopic observations. Geology, Geophysics and Environment 40 (2), 241-254.

Trąbska J., Wesełucha-Birczyńska A. and Trybalska B. 2014. Black crust on the surface of a flint artefact from Klementowice. In T. Wiśniewski (ed.), Klementowice. A Magdalenian site in Eastern Poland, Lublin : Wydawnictwo UMCS, 336-342.

Trąbska J. and Wesełucha-Birczyńska A. 2014. Badania fazowe i strukturalne grafitowej zawieszki ze stanowiska Brzezie 17, gm. Kłaj/Phase and structural studies of the graphite pendant from Brzezie 17, commune Kłaj. In A. Czekaj-Zastawny (ed.), Brzezie 17, osada kultury ceramiki wstęgowej rytej ( = Via Archaeologica. Źródła z badań wykopaliskowych na trasie autostrady A4 w Małopolsce). Kraków Krakówski Zespół do Badań Autostrad, 491-498.

Trąbska J., Wesełucha-Birczyńska A., Zięba-Palus J. and Runge M.T. 2011. Black painted pottery, Kildehuse II, Odensee County, Denmark. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 79 (4), 824-830.

Trąbska J., Trybalska B., Gaweł A. and Bytnar K. 2003. I. Pigmenty i warstwy malarskie ceramiki neolitycznej kultury trypolskiej (Bilcze Złote) II. Zabytki kamienne z Bilcza Złotego. Materiały Archeologiczne 34, 179-194.

Vázquez C., Maier M.S., Parera S.D., Yacobaccio H. and Solá P. 2008. Combining TXRF, FT-IR and GC-MS information for identification of inorganic and organic components in black pigments of rock art from Alero Hornillos 2 (Jujuj, Argentina). Analytical and Bioanalytical Chemistry 391, 1381-1387.

Waleńczak Z. 1987. Geochemia organiczna. Warszawa : Wydawnictwa Geologiczne.

Wilhelm H.A., Croset B.and Medjahdi G. 2007. Proportion and dispersion of rhomboedral sequences in the hexagonal structures in graphite powders. Carbon 45, 2356-2364.

Wiłkojć E. 2018. Konserwacja obrazów wielkoformatowych w Zamku Królewskim na Wawelu. In J. Ziętkiewicz-Kotz (ed.), Sztuka konserwacji – konserwacja sztuki. Katalog wystawy. Kraków: Drukarnia Pasaż, 39-48.

Winter J. and West FitzHugh E. 2007. Pigments Based on Carbon. In Berrie B.H. (ed.). Artistst’ Pigments . A Handbook of Their History and Characteristics, Vol.4. London : Washington and Archetype Publications.

Witruwiusz 2000. O architekturze ksiąg dziesięć/De Architectura Libri Decem. Przekład: K. Kumaniecki. Warszawa: Prószyński i S-ka.

Web sources

https//asbury.com (access 10.06.2020)

www.chiemgau-impact.com (access 15.05.2019)

www.mindat.org (access 15.05.2020)

http://naukawpolsce.pap.pl/aktualnosci/news%2C408318%2Cceltyccy-mincerze-w-Krakówie.html (access 15.05.2020)

https://www.silesiakultura.pl/r/miasta/zabrze/zabrze/wystawa-rzezby-w-weglu-i-graficie-symbol-gorniczego-trudu (access 15.05.2020)

Opublikowane

2020-12-30

Jak cytować

Trąbska, J. (2020). Graphite in an archaeological context comparing to other black substances – research problems and prospects. Ana­lecta Archa­eolo­gica Res­so­viensia, 15, 17–29. https://doi.org/10.15584/anarres.2020.15.2

Numer

Dział

Artykuły